Ask an Expert - Advancing Synthesis: Mechanistic Understanding and Size Control of Zirconium and Hafnium Oxide Nanocrystals

In contemporary times, the facile generation of monodispersed colloidal nanocrystals is achievable, yet a retro synthetic analysis remains elusive due to a frequently unclear underlying mechanism. The development of a comprehensive mechanistic model holds the potential to furnish essential scientific insights into the chemical system, fostering innovation in synthetic methodologies.

This study aims to unravel the formation mechanism in surfactant-assisted non-aqueous synthesis of zirconia and hafnia nanocrystals. Initially, active precursor species in the reaction mixture are identified utilizing a robust amalgamation of nuclear magnetic resonance (NMR) spectroscopy, in situ X-ray pair distribution function (PDF) analysis, gas chromatography (GC-FID), and density functional theory (DFT) calculations. Subsequently, focus shifts to the nucleation and growth mechanisms. X-ray scattering techniques are employed to explore the atomic-scale structural evolution and estimate particle concentrations.

The findings indicate the initial formation of numerous amorphous particles, followed by a decrease in total particle concentration as the amorphous particles undergo recrystallization into ZrO2 nanocrystals over time. The non-classical nucleation phenomenon appears to be linked to the decomposition rate of the precursor, which exceeds the observed crystallization rate by an order of magnitude.

A comprehensive comprehension of the nanoparticles' crystal structure is poised to establish a structure-function correlation. The synergistic insights gleaned from precursor chemistry and crystal growth are anticipated to facilitate the rational design and synthesis of intricate oxide nanocrystals, thereby serving as pivotal constituents in material science endeavors.

Who should attend? 

• Researchers and Scientists working in the field of nanomaterials, particularly those focusing on the synthesis and characterization of nanocrystals
• Technical Experts and Instrumentation Specialists working in the field of X-ray scattering
• Graduate and postgraduate students pursuing research in nanomaterials, seeking to understand advanced synthesis and characterization of nanocrystals
• Industry Professionals: those involved in the design and development of nanomaterials for various applications, including catalysis, electronics, and biomedical fields

What will you learn? 

• Understand the formation mechanism of ZrO2/HfO2 nanocrystals
• Gain insights into how X-ray scattering techniques are utilized to study the atomic-scale structural evolution during nanocrystal synthesis
• Learn the importance of correlating the crystal structure of nanoparticles with their functional properties
• Appreciate the significance of developing genuine mechanistic models in advancing synthetic strategies for nanocrystal production